Unit 1: Chemistry of Life

AP Biology: 149 practice questions with detailed explanations.

Unit Study Guide

Executive Summary

Unit 1 builds the molecular toolkit: water's chemistry, the CHNOPS elements of life, and the four macromolecule classes. Structure determines function at every level.

Water and hydrogen bonding

Water's bent shape and polar O–H bonds let each molecule donate and accept hydrogen bonds. That network produces cohesion (water sticking to water), adhesion (sticking to other surfaces), high specific heat, high heat of vaporization, expansion on freezing, and ice floating. Water is a universal solvent for polar and ionic solutes.

Elements of life

CHNOPS — carbon, hydrogen, nitrogen, oxygen, phosphorus, sulfur — dominate biomolecules. Carbon's four valence electrons allow branching skeletons and isomers. Nitrogen appears in proteins and nucleic acids; phosphorus in ATP and DNA backbones; sulfur in some amino acids.

Macromolecules

Carbohydrates store energy and provide structure (starch, glycogen, cellulose, chitin). Lipids are nonpolar hydrocarbons: fats for storage, phospholipids for membranes, steroids for signaling. Proteins are amino-acid polymers folded into structures that enzymes and transporters require. Nucleic acids (DNA, RNA) store and transmit information.

Dehydration synthesis and hydrolysis

Polymers grow by dehydration synthesis (monomers join, water released) and break by hydrolysis (water consumed). Both directions are enzyme-catalyzed.

Protein shape comes from the amino-acid sequence: R-group interactions (hydrophobic packing, hydrogen bonds, disulfide bridges) fold chains into functional shapes. Nucleic-acid sequence encodes protein sequence; DNA strands pair by complementary base pairing (A–T, G–C).

Top 5 Concepts to Master

  1. 1Trace water's emergent properties to hydrogen bonding between polar H₂O molecules.
  2. 2Identify the four macromolecule classes by monomer and bond type.
  3. 3Connect dehydration synthesis and hydrolysis as reverse reactions.
  4. 4Explain protein structure–function using R-group interactions.
  5. 5Apply complementary base pairing to DNA strand prediction.

Key Terms & Definitions

Practice with Flashcards
Hydrogen bond

Attraction between a partially positive H and an electronegative atom (N, O, F).

Cohesion

Attraction between molecules of the same substance (water–water).

Adhesion

Attraction between molecules of different substances (water–glass).

Specific heat

Energy needed to raise 1 g of a substance by 1 °C; water's is unusually high.

Hydrophilic

Water-loving; polar or charged.

Hydrophobic

Water-avoiding; nonpolar.

Monomer

Small building block of a polymer.

Polymer

Chain of covalently linked monomers.

Dehydration synthesis

Joining monomers with the release of a water molecule.

Hydrolysis

Breaking a polymer by adding water.

Monosaccharide

Single sugar such as glucose.

Amino acid

Molecule with amino, carboxyl, and R groups; protein monomer.

Nucleotide

Sugar + phosphate + nitrogenous base; nucleic-acid monomer.

Complementary base pairing

A pairs with T (U in RNA); G pairs with C.

Common Misconceptions: Exam Traps

Only water molecules hydrogen bond with each other.

Correct: Any molecule with N–H, O–H, or F–H groups can hydrogen bond — including proteins and DNA bases.

Lipids are polymers of fatty acids.

Correct: Lipids are not built from a single repeating monomer; fats assemble from glycerol + fatty acids in one step.

Proteins fold into their shape by chance.

Correct: Sequence-encoded R-group interactions drive specific, reproducible folding; denaturation unravels but does not destroy the chain.

All bonds in biomolecules are equally strong.

Correct: Covalent bonds hold atoms; weaker hydrogen bonds and van der Waals forces shape structures and interactions.

Ice floats because it traps air bubbles.

Correct: Ice floats because its hydrogen-bonded lattice spaces molecules farther apart than liquid water — lower density.

Question Bank Breakdown

By difficulty

easy 62medium 74hard 13

By topic

Structure and Function of Macromolecules 37Introduction to Biological Macromolecules 30Structure of Water and Hydrogen Bonding 28Nucleic Acids 21Properties of Biological Macromolecules 19Elements of Life 16Structure and Function of Biological Macromolecules 14Macromolecule Structure and Function 7

All Questions in this Unit