AP Chemistryhardmcq1 pt

A proposed mechanism begins with the slow step A + B -> P. Experimentally, doubling [A] alone while holding [B] constant quadruples the initial rate. What follows about the proposed mechanism?

A.It must be revised, because its slow step predicts first order in A
B.It is confirmed, since the rate depends on A as the step suggests
C.It fails only if the reaction absorbs heat
D.Nothing can be concluded, because mechanisms never predict rate laws

Explanation

Core Concept

If the slow step really were A + B -> P, its molecularity would force rate = k[A][B], so doubling [A] alone should merely double the rate. The observed quadrupling shows second-order behavior in A, contradicting the proposal. Kinetic data can disprove a candidate mechanism, and this disagreement demands revision. Consistency alone never proves a mechanism, but inconsistency certainly rejects one.

Correct Answer

AIt must be revised, because its slow step predicts first order in A

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