AP Chemistrymediummcq1 pt

The photoelectron spectrum of boron shows three peaks ordered from highest to lowest binding energy with relative areas 2:2:1. What is boron's ground-state electron configuration?

A.1s2 2s2 2p1
B.1s2 2s2 2p3
C.1s2 2s1 2p2
D.1s2 2s2 2p2

Explanation

Core Concept

Peak area counts the electrons in a subshell, and binding energy falls with distance from the nucleus. Reading from core outward, the 2:2:1 pattern maps to 1s with two electrons, 2s with two, and 2p with one. Five electrons total matches boron's atomic number, confirming 1s² 2s² 2p¹.

Correct Answer

A1s2 2s2 2p1

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