Unit 7: Atmospheric Pollution

AP Environmental Science: 50 practice questions with detailed explanations.

Unit Study Guide

Executive Summary

Unit 7 covers outdoor and indoor air pollution: how smog forms, what acid rain does, and how regulation cleaned the air.

Photochemical smog

Sunlight drives NOx + VOCs to form tropospheric ozone and smog, worst in sunny cities with traffic (Los Angeles). Thermal inversions trap it: a warm layer sits above cool air, blocking dispersal — common in valley cities.

Primary and secondary pollutants

Primary pollutants are emitted directly (CO, particulates, SO₂, NOx, VOCs). Secondary pollutants form in the air: ozone, sulfuric and nitric acids, PANs. Particulate matter (PM2.5, PM10) penetrates lungs.

Acid deposition

SO₂ (coal) and NOx form sulfuric and nitric acids that fall as acid rain, lowering pH of lakes and soils and leaching nutrients. Lime can buffer lakes; scrubbers remove SO₂ at the source.

Indoor air

Radon (radioactive soil gas) causes lung cancer; formaldehyde, VOCs, asbestos, and carbon monoxide threaten indoors. Ventilation is the cheapest fix.

Regulation

The Clean Air Act (1970) set national standards for six criteria pollutants and drove catalytic converters and scrubbers. The Montreal Protocol (1987) phased out CFCs, healing stratospheric ozone — the most successful environmental treaty.

Exam traps

Stratospheric ozone is protective; tropospheric ozone is a pollutant — same molecule, different altitude. Thermal inversions worsen smog by trapping it. The Montreal Protocol addressed ozone, not climate (though CFCs are also greenhouse gases).

Top 5 Concepts to Master

  1. 1Classify pollutants as primary vs secondary.
  2. 2Explain smog formation from NOx + VOCs + sunlight.
  3. 3Trace acid deposition from SO₂/NOx to lake acidification.
  4. 4Connect thermal inversions to severe smog episodes.
  5. 5Compare the Clean Air Act and Montreal Protocol outcomes.

Key Terms & Definitions

Practice with Flashcards
Primary pollutant

Emitted directly from a source.

Secondary pollutant

Formed in air from primary pollutants.

Photochemical smog

Sunlight-driven ozone and PAN haze from NOx + VOCs.

Thermal inversion

Warm air cap trapping cool, polluted air below.

Tropospheric ozone

Ground-level pollutant harming lungs.

Particulate matter

Suspended particles (PM2.5, PM10).

Acid deposition

Acid rain/fog from SO₂ and NOx.

Radon

Radioactive gas from uranium decay in soil.

VOC

Volatile organic compound from paints, fuels, solvents.

Catalytic converter

Device reducing vehicle CO, NOx, and VOCs.

Scrubber

Removes SO₂ from smokestack exhaust.

Clean Air Act

1970 US law regulating criteria pollutants.

Montreal Protocol

1987 treaty phasing out CFCs.

Criteria pollutant

Six regulated pollutants: CO, Pb, NO₂, O₃, PM, SO₂.

Common Misconceptions: Exam Traps

Ozone is always harmful.

Correct: Stratospheric ozone shields UV; only ground-level ozone is a pollutant.

The Montreal Protocol was a climate treaty.

Correct: It targeted ozone depletion; CFCs' climate benefit was a bonus.

Thermal inversions cause pollution.

Correct: Inversions trap existing pollution; they do not emit it.

Smog forms fastest at night.

Correct: Photochemical smog needs sunlight — peak in the afternoon.

Acid rain only affects lakes.

Correct: It also leaches soil nutrients, corrodes buildings, and harms forests.

Question Bank Breakdown

By difficulty

easy 19medium 29hard 2

By topic

Acid Deposition 11Air Quality Regulations 10Indoor Air Pollutants 9Photochemical Smog 8Clean Air Act 7CO and Particulates 6Thermal Inversion 4VOCs 3Radon 3Montreal Protocol 2

All Questions in this Unit